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My all time favorite Buffy fanfic is descant descending, by macha.

0.2.3 INCEPTION/ DIVINATION/ FATES

Before the World, the Word.

But even before the Word, the First Slayer began in silence, and her power rose with her out of Darkness to exist only in the moment of Death.

And it came to pass that as one died, the next was called, throughout recorded time.

But when the earth beneath wakes hungry, then one will come, and die, and two shall rise, one light, one dark, and the dark one shall covet light, and the light one shall fall into darkness.

The Slayer that was will drown, and the Slayer that is will jump, and the Slayer that shall be will storm the gates of the underworld.

And then in the final days either the Slayer will shatter or she will shatter the walls between dimensions, depending on whom she chooses to stand with her, and in any event this will be known in the demon worlds as the end of days.

Above all fics I might point people too, I encourage people the strongest to read this one. It's so creative and thoroughly presented, it makes me drool.

Close runner-ups:
Spiegel Im Spiegel by Fallowdoe
Daemons Luminati (a.k.a. Radiance), by